Can Orbitals Really Be Observed in Scanning Tunneling Microscopy Experiments?

Have Orbitals Really Been Observed?

1492 Journal of Chemical Education • Vol. 77 No. 11 November 2000 • JChemEd.chem.wisc.edu The purpose of this article is to comment on the pedagogical ramifications of the recently claimed observation of d orbitals and the way in which these results were first announced and subsequently reported (1–6 ). Atomic orbitals—their use in writing electronic configurations and as a means of rationalizi...

Scanning tunneling microscopy experiments on single molecular landers.

Molecular landers are molecules comprising of a central rigid molecular wire maintained above a metallic surface by organic spacers, which allows specific ultrahigh vacuum-scanning tunneling microscopy experiments to be performed at the single-molecule level. The understanding of the molecule-surface interactions, intramolecular mechanics, and the possibility to perform extremely precise tip-in...

Microscopy, Scanning Tunneling

Ultrafast Scanning Tunneling Microscopy

Scanning Tunneling Microscopy

The invention of the scanning tunneling microscope was a singularity event in the field of surface science and condensed matter physics. The ability to visualize individual atoms in an atomic structure was a huge step forward in experimental development, one for which the inventors were awarded the Nobel Prize in Physics in 1986. While a groundbreaking development, the Scanning Tunneling Micros...